Metallosupramolecular Silver and Zinc Complexes with Flexible or Semirigid Tripodal Pyridyl Pyrimidine Ligands

doi:10.1007/s10904-015-0169-6

	Metallosupramolecular Silver and Zinc Complexes with Flexible or Semirigid Tripodal Pyridyl Pyrimidine Ligands
	Dong, Huaze 1; Liu, Xia 2; Zheng, Bin 1; Wang, Yanping 1; Ling, Bo 1; Pin, Zongxin 1; Bi, Jianhong 1; Gou, Shaohua 3
	2015-03
发表期刊	JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
ISSN	1574-1443
卷号	25 期号:2 页码:318-326
摘要	To explore the influence of different transition metal ions on the coordination geometries and structural architectures of metal organic complexes with flexible or semirigid tripodal ligands, [(Zn3C36H27N9S3I6)center dot(CHCl3)(4)](1), [C33H30N10S3Zn3Cl6] (2) and {[Ag-2(C33H30N10S3)NO3]center dot NO3 center dot H2O}(n)(3) were yielded by reactions of three tripodal ligands derived from pyridinyl-pyrimidine-2-thiol with ZnI2, ZnCl2 and AgNO3, respectively. The structural motifs of these complexes are multiforms from 0D to 3D interpenetrating networks. It is found that the conformational changes of ligands after interactions with metal salts are attributed to the positional isomerization of pyridine ring and effects of metal ions as well as anions. The pyridyl and pyrimidinyl rings act as N<^>N chelation or adopt monodentate mode in these complexes. The anions all take part in coordinating metal ions especially nitrates which can bridge silver ions to produce 1D structure in complex 3.
关键词	Metallosupramolecular COPPER(II) COMPLEXES Pyridinyl-pyrimidine-2-thiol Crystal structure
DOI	10.1007/s10904-015-0169-6
收录类别	SCIE
语种	英语
WOS研究方向	Polymer Science
WOS类目	Polymer Science
WOS记录号	WOS:000350360500016
出版者	SPRINGER
原始文献类型	Article
EISSN	1574-1451
引用统计	被引频次[WOS]：0 [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.library.ouchn.edu.cn/handle/39V7QQFX/168357
专题	国家开放大学江苏分部
通讯作者	Dong, Huaze
作者单位	1.Hefei Normal Univ, Dept Chem & Chem Engn, Hefei 230061, Peoples R China; 2.Jiangsu Open Univ, Dept Sci & Technol, Nanjing 210036, Jiangsu, Peoples R China; 3.Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Dong, Huaze,Liu, Xia,Zheng, Bin,et al. Metallosupramolecular Silver and Zinc Complexes with Flexible or Semirigid Tripodal Pyridyl Pyrimidine Ligands[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2015,25(2):318-326.
APA	Dong, Huaze.,Liu, Xia.,Zheng, Bin.,Wang, Yanping.,Ling, Bo.,...&Gou, Shaohua.(2015).Metallosupramolecular Silver and Zinc Complexes with Flexible or Semirigid Tripodal Pyridyl Pyrimidine Ligands.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,25(2),318-326.
MLA	Dong, Huaze,et al."Metallosupramolecular Silver and Zinc Complexes with Flexible or Semirigid Tripodal Pyridyl Pyrimidine Ligands".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 25.2(2015):318-326.