A new two-dimensional cadmium(II) coordination polymer based on the asymmetric dicarboxylic acid homophthalic acid: synthesis, structure and properties

doi:10.1107/S2053229622008476

	A new two-dimensional cadmium(II) coordination polymer based on the asymmetric dicarboxylic acid homophthalic acid: synthesis, structure and properties
	Shen, Hong 1,2
	2022-09
发表期刊	ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
ISSN	2053-2296
卷号	78 页码:481-+
摘要	A new coordination polymer poly[[mu(2)-4,4'-bis(2-methylimidazol-1-yl)biphenyl-kappa N-2(3):N-3']bis[mu(3)-2-(2-carboxylatophenyl)acetato-kappa O-5,O':O',O '':O '']dicadmium(II)], [Cd(C9H6O4)(C20H18N4)(0.5)](n) or [Cd(HMPH)(4,4'-BMIBP)(0.5)](n) [H2HMPH is homophthalic acid and 4,4'-BMIBP is 4,4'-bis(2-methylimidazol-1-yl)biphenyl], (I), was synthesized by the solvothermal method and was structurally characterized by means of single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Coordination polymer (I) exhibits a two-dimensional layer based on one-dimensional [Cd(HMPH)](n) chains. Remarkably, photocatalytic degradation experiments on methylene blue (MB) indicated that (I) exhibits an obvious degradation effect. Moreover, an investigation of the luminescence properties of (I) revealed that it could be considered as a potential highly selective luminescence sensor for nitrofurantoin (NFT).
关键词	coordination polymer METAL-ORGANIC FRAMEWORKS 4,4'-bis(2-methylimidazol-1-yl)biphenyl SERIES crystal structure ZN homophthalic acid fluorescence recognition photocatalytic degradation
DOI	10.1107/S2053229622008476
收录类别	SCIE
语种	英语
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Multidisciplinary ; Crystallography
WOS记录号	WOS:000852661700003
出版者	INT UNION CRYSTALLOGRAPHY
原始文献类型	Article
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.library.ouchn.edu.cn/handle/39V7QQFX/168546
专题	国家开放大学江苏分部
通讯作者	Shen, Hong
作者单位	1.Jiangsu Open Univ, Nanjing 210036, Peoples R China; 2.Southeast Univ, Jiangsu Prov High Tech Key Lab Biomed Res, Nanjing 211189, Peoples R China
第一作者单位	国家开放大学江苏分部
通讯作者单位	国家开放大学江苏分部
第一作者的第一单位	国家开放大学江苏分部
推荐引用方式 GB/T 7714	Shen, Hong. A new two-dimensional cadmium(II) coordination polymer based on the asymmetric dicarboxylic acid homophthalic acid: synthesis, structure and properties[J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY,2022,78:481-+.
APA	Shen, Hong.(2022).A new two-dimensional cadmium(II) coordination polymer based on the asymmetric dicarboxylic acid homophthalic acid: synthesis, structure and properties.ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY,78,481-+.
MLA	Shen, Hong."A new two-dimensional cadmium(II) coordination polymer based on the asymmetric dicarboxylic acid homophthalic acid: synthesis, structure and properties".ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY 78(2022):481-+.